Fe-based metallic glasses are ideal candidates to be utilized in transformer cores owing to their outstanding soft magnetic properties. However, they are difficult to machine properly by conventional means due to their mechanical brittleness and poor thermal conductivity. Here, the cutting of Fe91–Si4.5–C4.0–Al0.5 amorphous alloy ribbons is reported with a sub-50 fs laser pulses. A systematic study is performed on local morphological and chemical composition changes to the machined edge in comparison to crystalline metals. It is shown that only the innermost 80 (Formula presented.) m wide region of the cut edge shows any detectable modifications, which is much less than for continuous laser machining. Therefore, the proposed method is indeed a valuable approach to overcome the fine machining difficulties of metallic glasses.