In our study, we compare the surface modifications of coarse HDPE surface induced by atmospheric air plasma, CO2 laser, and flame treatments. An order of WCA decrease of air plasma>flame>CO2 laser methods was detected. The improvement in adhesion strength measured 5 days after the activations followed the same trend. FT-IR and EDS proved that different oxygen compounds were formed after treatments, resulting in increased polar component of the total surface energy. Flame activation showed a saturation character regarding the O-moiety. Hydrophobic recovery showed a linear behavior, with a larger decreasing slope for the polar component than the total surface energy. Plasma treatments induced higher recovery rate; however, restore was not complete here either. The effects of the different CO2 irradiation intensities were nonlinear; SEM and roughness measurements revealed surface ablation or structure formation on the different samples, while after plasma and flame treatment a hilly microtexture appeared. With different mechanisms and intensities, all the tested methods are suitable for increasing the adhesion strength on HDPE surfaces.

The use and significance of adhesives in various industries are explored, highlighting the growth of the adhesive market and the crucial role of time in adhesive bonding. The composition of adhesives, particularly polyurethane adhesives (PUR), is detailed, emphasizing their sensitivity to environmental factors, like moisture and UV radiation. Various factors influencing adhesive properties, such as reactivity and curing-induced shrinkage, are discussed, along with the importance of catalysts in adjusting reaction rates. One-component moisture-curable PUR adhesives are presented as versatile and continually improving alternatives in structural adhesive applications. The research's focus was to investigate the curing speed of Sikaflex-252 1-component PUR structural adhesive under different conditions, including room temperature, room temperature with ~30% humidity, and room temperature with ~100% humidity.

This study explores the tensile strength of adhesive joints in steel, focusing on the influence of heat treatment and diverse surface modifications. Results indicate a notable relationship between annealing temperature and tensile strength, with the most favorable outcomes identified at 90 min and 165 °C. Particularly, surfaces treated through turning, sandblasting, and plasma treatment (type C) consistently outperformed other methods. A standout revelation emerged from the turned, sandblasted, and plasma-treated surface (C), showcasing an exceptional tensile strength of 69.06 MPa. Load-holding tests underscored its resilience under diverse load conditions. Surface analyses, including roughness measurements, wetting characteristics, and Scanning Electron Microscope imaging, provided valuable insights into structural transformations induced by different treatments. Chemical composition examinations unveiled significant alterations post-plasma treatment, impacting surface chemistry and contributing to an outstanding tensile strength of 67.63 MPa. In essence, this research offers a glimpse into the nuanced factors influencing adhesive joint strength in steel. The turned, sandblasted, and plasma-treated surface emerges as a promising avenue, sparking further curiosity into the underlying mechanisms propelling superior tensile strength in adhesive joints.