For any country, the availability of electricity is crucial to the development of the national economy and society. As a result, decision-makers and policy-makers can improve the sustainability and security of the energy supply by implementing a variety of actions by using the evaluation of these factors as an early warning system. This research aims to provide a multi-criterion decision-making (MCDM) method for assessing the sustainability and security of the electrical supply. The weights of criteria, which indicate their relative relevance in the assessment of the sustainability and security of the energy supply, the MCDM method allow users to express their opinions. To overcome the impact of uncertainty and vagueness of expert opinion, we explore the notion of picture fuzzy theory, which is a more efficient and dominant mathematical model. Recently, the theory of Aczel-Alsina operations has attained a lot of attraction and has an extensive capability to acquire smooth approximated results during the aggregation process. However, Choquet integral operators are more flexible and are used to express correlation among different attributes. This article diagnoses an innovative theory of picture fuzzy set to derive robust mathematical methodologies of picture fuzzy Choquet Integral Aczel-Alsina aggregation operators. To prove the intensity and validity of invented approaches, some dominant properties and special cases are also discussed. An intelligent decision algorithm for the MCDM problem is designed to resolve complicated real-life applications under multiple conflicting criteria. Additionally, we discussed a numerical example to investigate a suitable electric transformer under consideration of different beneficial key criteria. A comparative study is established to capture the superiority and effectiveness of pioneered mathematical approaches with existing methodologies.