Csaba Centeri

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Publications - 7

Beyond land use: Understanding variations in topsoil bulk versus recalcitrant organic matter

Tibor Filep Gabriella Darabos Csaba Centeri Zsuzsanna Angyal Balázs Madarász András Bidló Viktoria Vona Ákos Bede-Fazekas Gábor Szatmári Dóra Zacháry Csilla Király Máté Karlik Anna Vancsik Thulfiqar Al-Graiti Malihe Masoudi Zoltán Dévény Zoltán Szalai Gergely Jakab

Publication Name: Catena

Publication Date: 2024-09-01

Volume: 244

Issue: Unknown

Page Range: Unknown

Description:

Soil organic matter (SOM) concentration and composition are essential properties that affect most functions and ecosystem services. The relationship between soil and environmental covariates regarding SOM concentration and composition in various pools is not completely understood. This study aimed to identify the most influential drivers of SOM stabilization, focusing on arable lands in Hungary. Hungary is an ideal area for investigating SOM variability because it is at the meeting point of the three main climate effects that trigger a wide range of soil, land use, and topographical conditions. Overall, 87 soil samples were taken from the topsoil (2–20 cm) and fractionated (<20 µm) to separate the mineral phase-associated organic carbon (MAOC) and bulk pools. MAOC concentration varied on a wide range (0.5–14.1 %) and was the function of bulk SOM aromaticity and slope steepness, rather than land use, climatic conditions, or soil properties, indicating that MAOC is also affected by decomposition if the bulk OM is less available for the microbiome. Land use, especially in forest topsoils, reflects the elemental composition of the OM, focusing on the variations of residue composition. In contrast, aromaticity is rather related to soil and climate properties, suggesting increased relevance of transformation processes. As a consequence, SOM composition varies on a wide range in the topsoil, however, the lack of a definite trend at the county level suggests the complexity of the system and highlights the role of local circumstances.

Open Access: Yes

DOI: 10.1016/j.catena.2024.108232

Effect of pH, Carbonate and Clay Content on Magnesium Measurement Methods on Hungarian Soils

Csaba Centeri Renato Kalocsai Márton Vona Zsolt Biró Viktoria Vona Tamás Szakál István Mihály Kulmány Sándor Zsebő Lajos Kubina Zsolt Giczi

Publication Name: Soil Systems

Publication Date: 2024-06-01

Volume: 8

Issue: 2

Page Range: Unknown

Description:

More exact information on soil nutrient management is crucial due to environmental protection, nature conservation, decreasing sources for mining, general precaution, etc. Soil magnesium (Mg) analytical methods of potassium chloride (KCl), Mehlich 3 (M3), water (WA) and cobalt hexamine (CoHex) extractions are compared with an elemental analysis and X-ray fluorescence (XRF) analysis. The ratio of the available to the total Mg content was calculated and compared on the whole dataset. The results showed that the linear regressions between all the pairs of Mg content measurement methods were significant. The linear relationship between the KCl and CoHex methods has the highest determination coefficient (R2 = 0.96), followed by WA–M3 (R2 = 0.68), M3–CoHex (R2 = 0.66) and M3–KCl (R2 = 0.60). The M3 solution demonstrated a greater capacity for extracting Mg from the soil. The second part is the analysis of the influence of CaCO3, pH, soil texture and clay content on the measurable magnesium content of soils. It was established that the extraction methods, the soil and the classification method of the soil properties affect the evaluation. These results may help through the nutrient replenishment and the melioration of soils. These results can help the examination of mineral nutrients, especially the Mg uptake.

Open Access: Yes

DOI: 10.3390/soilsystems8020049

The effect of local samples in the accuracy of mid-infrared (MIR) and X-ray fluorescence (XRF) -based spectral prediction models

Csaba Centeri Renato Kalocsai G. Milics Márton Vona Viktoria Vona B. Tomczyk A. Vér István Mihály Kulmány S. Sarjant Gergely Jakab

Publication Name: Precision Agriculture

Publication Date: 2022-12-01

Volume: 23

Issue: 6

Page Range: 2027-2039

Description:

Within the soil spectroscopy community, there is an ongoing discussion addressing the comparison of the performance of prediction models built on a global calibration database, versus a local calibration database. In this study, this issue is addressed by spiking of global databases with local samples. The soil samples were analysed with MIR and XRF sensors. The samples were further measured using traditional wet chemistry methods to build the prediction models for seventeen major parameters. The prediction models applied by AgroCares, the company that assisted in this study, combine spectral information from MIR and XRF into a single ‘fused-spectrum’. The local dataset of 640 samples was split into 90% train and 10% test samples. To illustrate the benefits of using local calibration samples, three separate prediction models were built per element. For each model, 0%, 50% (randomly selected) and 100% of the local training samples were added to the global dataset. The remaining 10% local samples were used for validation. Seventeen soil parameters were selected to illustrate the differences in performance across a range of soil qualities, using the validation set to measure performance. The results showed that many models already exhibit an excellent level of performance (R2 ≥ 0.95) even without local samples. However, there was a clear trend that, as more local calibration samples were added, both R2 and ratio of performance to interquantile distance (RPIQ) increase.

Open Access: Yes

DOI: 10.1007/s11119-022-09942-y

Comparing Different Phosphorus Extraction Methods: Effects of Influencing Parameters

Csaba Centeri Renato Kalocsai G. Milics Márton Vona Zsolt Biró Viktoria Vona A. J. Kovács J. Kauser István Mihály Kulmány Gergely Jakab

Publication Name: Sustainability Switzerland

Publication Date: 2022-02-01

Volume: 14

Issue: 4

Page Range: Unknown

Description:

The current study compares the phosphorus (P) analysis methods of ammonium lactate (AL), Mehlich 3 (M3); water extraction (P-WA(P)&P-WA(PO4 )), cobalt hexamine (CoHex) and X-ray fluorescence (XRF) as an estimate of total soil P. The ratio of the P-content/XRF was first calculated and compared with the whole dataset. Based on the comparison of all the data, there were significant differences between the results of P-WA(P) and P-WA(PO4 ) vs. M3 and AL, CoHex vs. M3 and CoHex vs. AL methods (p < 0.001). The second step was the analysis of the influencing factors based on their categories for a more in-depth understanding of their role (CaCO3-content, pH, soil texture and clay content). The results showed that higher CaCO3 content (>1%) resulted in lower correlations (6/10 cases). The extraction methods, the soil, the classification method of the soil properties and the statistical analyses affect the evaluation. The dataset covers a good range of the analysed factors for the evaluation of phosphorus in the majority of Hungarian soil types in arable use. There were two methods that detected the largest amount of P from the total P in the soil: AL and M3.

Open Access: Yes

DOI: 10.3390/su14042158

The effect of soil physicochemical characteristics on zinc analysis methods

Csaba Centeri Renato Kalocsai G. Milics Zsolt Biró Viktoria Vona A. J. Kovács Endre Andor Tóth István Mihály Kulmány Gergely Jakab Zsolt Giczi

Publication Name: Soil and Water Research

Publication Date: 2021-01-01

Volume: 16

Issue: 3

Page Range: 180-190

Description:

Zn is an essential micronutrient involved in a wide variety of physiological processes. Soils are tested for zinc in many countries with several extractants. Each country has its validated methods, best-suited for its soils. The current study was designed to compare different zinc content measuring methods with seventy-one samples from Hungary. The data were first compared for the whole dataset and then in certain categories such as CaCO3-content, pH, texture and clay content. The zinc content was determined by the water extraction, KCl-EDTA (ethylenediaminetetraacetic acid), Mehlich 3, CoHex (cobalt hexamine trichloride), and XRF (X-ray fluorescence) methods. Based on the analyses of all the data, we can conclude that all the methods are different. However, further analyses during the comparison of the methods based on the influencing factors, such as the pH, lime content, texture class, and clay content proved that, in some of the cases, there are similarities among the methods and, this way, we can get more knowledge on the measurements and the results provided. Farmers can gain extra knowledge from the comparison of the influencing factors to know where intervention is needed to use extra Zn for the proper fertilisation of their plants.

Open Access: Yes

DOI: 10.17221/53/2020-SWR

Past-present-future in hungarian soil analyses

Csaba Centeri Renato Kalocsai Márton Vona Viktoria Vona István Mihály Kulmány István Attila Bakos Zsolt Giczi

Publication Name: Agrokemia Es Talajtan

Publication Date: 2020-12-01

Volume: 69

Issue: 1

Page Range: 127-151

Description:

The purpose of the present paper isAuthors aim was to deliver a compilation of to summarize the Hungarian soil analysies methods and theas well as to present the advisory system for nutrient management advisory system. Both of them are based on several decades of work. We need to should learn from these past experiences of reasonable and good agricultural practices. We can only apply the present and future results of soil science and find out what direction should we develop, if we were aware of the results of the past and we calculate with their governing effects. The majority of our recent methods are based on historical researches and the present current statesituation of our field of scientific fieldce can only be judged and developed further if we knew the former history of the methodological findings. The recent Hungarian soil analysis system provides useful results that can be used very well today, however, the adaptation of the new international methods, learned from the follow-up of the international trends can might provide open new perspectives in for the Hungarian laboratory analyses methodology. TThe subject is extremely timely because there are hea never- met demand for cost and time effective, environmentally friendly soil analysis methods underpin how actual and hot the topic is. nowadays.

Open Access: Yes

DOI: 10.1556/0088.2020.00061

Comparison of magnesium determination methods on Hungarian soils

Csaba Centeri Renato Kalocsai G. Milics Zsolt Biró Viktoria Vona A. J. Kovács Gergely Jakab Zsolt Giczi

Publication Name: Soil and Water Research

Publication Date: 2020-01-01

Volume: 15

Issue: 3

Page Range: 173-180

Description:

Magnesium is one of the most important nutrient elements. Soils are tested for magnesium in many countries with several extractants. Each country has its own validated methods, best-suited for its soils. The current study was designed to compare different magnesium content measuring methods with 80 Hungarian samples. The magnesium content was determined by the potassium chloride (1 M KCl 1:10), Mehlich 3 and CoHex (cobalt hexamine trichloride) methods. The maximum, mean and median values resulting from all the Mg determination methods showed the following order of measured magnitude: KCl < CoHex < M3.

Open Access: Yes

DOI: 10.17221/92/2019-SWR