Publication Name: Chemical Engineering Transactions
Publication Date: 2024-01-01
Volume: 114
Issue: Unknown
Page Range: 1069-1074
Description:
The growth of the world's population is an increasing challenge for agricultural production. Improving soil productivity is the key to ensuring the quantity, quality and safety of food for a growing population. In addition to macroelements, microelements also play an important role in the biochemical processes. A large percentage of soils in Hungary show a deficiency in copper. For three years, we treated the leaves of winter wheat with a copper-tetramine-sulphate complex derived from microelectronic waste. Aim to provide an alkaline pH range of 9.3 for effective foliar treatment. Treatments were applied on 10 m2 small plots at 0; 0.1; 0.3; 0.5; 1.0; and 2.0 kg×ha-1 copper dose in the budding and flowering phenological stages with copper-tetramine-sulphate produced from microelectronic waste. After harvesting the crop from the plots, the yield, raw protein, and gluten content were measured. In the copper-deficient soil, a significant increase in yield and protein and gluten levels was observed after treatment with copper foliar fertiliser. The most significant increase in yield was obtained in the treatment at flowering (0.40 t/ha), with a 0.37 % increase in crude protein content and a 1.95 % increase in wet gluten content.
A crop growing in the right quantity and quality can only be secured if nutrients are provided in an adequate quantity and available form. Copper (Cu) has primary importance among microelements in growing winter wheat. Lack of Cu hinders nitrogen uptake by plants. Therefore, increasing bioavailability is important in crop production. It has been conducted successful foliar fertilisation experiments with Tetraamminecopper(II) sulphate for several years. The efficiency of the applied compound was enhanced by the application of a retarded nutrient-supply. To secure retardation, ion exchange was carried out in NaA type synthesized zeolite with Tetraamminecopper(II) sulphate. Structure of Tetraamminecopper(II) sulphate, and zeolite ion-exchanged by copper-tetraamine was analysed with a derivatograph and X-ray diffraction. Derivatograph analyses revealed heat stability. X-ray diffraction analyses revealed that copper-tetramine ions exchanged a significant part of the sodium ions of zeolite in ion exchange.