Tribological investigation of the effect of nanosized CuO and TiO2 on a base oil containing Komad 323 dispersant

Publication Name: Jurnal Tribologi

Publication Date: 2024-09-01

Volume: 42

Issue: Unknown

Page Range: 103-128

Description:

This article investigates the impact of copper(II) oxide (CuO) and titanium dioxide (TiO2) nanoparticles in Group III base oil with 8 wt% Komad 323 dispersant. Nanoparticles underwent ethyl oleate surface modification. Tribological properties were assessed using a linear oscillating tribometer, continuously monitoring static friction. Friction integral values were derived from extensive data acquisition. Wear analysis employed digital optical and confocal microscopy, complemented by scanning electron microscopy for wear-type characterization and energy-dispersive X-ray spectroscopy for additive quantification in the wear track. Results indicate CuO nanoparticles' poor compatibility with Komad 323, resulting in increased friction (2-13%) and substantial wear reduction (39-50%) at low CuO concentrations (≤0.3 wt%). Higher concentrations (≥0.4 wt%) reduced friction (21-35%) but led to surface fatigue and increased wear rates. Elemental composition analysis of the wear track revealed that the surface contains 1.43-3.17 norm.wt% copper. Conversely, TiO2 in synergy with the dispersant, formed a boundary layer, exhibiting lower friction by 11-14%. TiO2 formed a high wear resistance boundary layer at titanium concentrations of 0.33-0.39 norm.wt%, which resulted in 44% wear volume reduction. Applying both nanoparticles reduced the wear scar diameter of the test specimens by 3-12%.

Open Access: Yes

DOI: DOI not available

Authors - 3